Rout, Saroj Kumar ; Guin, Srimanta ; Banerjee, Arghya ; Khatun, Nilufa ; Gogoi, Anupal ; Patel, Bhisma K. (2013) Directing group assisted copper-catalyzed chemoselective o-aroylation of phenols and enols using alkylbenzenes Organic Letters, 15 (16). pp. 4106-4109. ISSN 1523-7060
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Official URL: https://pubs.acs.org/doi/abs/10.1021/ol401682a
Related URL: http://dx.doi.org/10.1021/ol401682a
Abstract
By using alkylbenzenes as aroyl surrogates, copper(II) catalyzed chemoselective O-aroylations of 1,3-dicarbonyl compounds and phenolic −OH ortho to carbonyl (−CHO, −COR) groups have been achieved. A dual mechanism operating in tandem for these transformations has been supported by a crossover experiment.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 113880 |
| Deposited On: | 02 May 2018 04:49 |
| Last Modified: | 02 May 2018 04:49 |
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