Rout, Saroj Kumar ; Guin, Srimanta ; Gogoi, Anupal ; Majji, Ganesh ; Patel, Bhisma K. (2014) Terminal aryl alkenes and alkynes as arylcarboxy surrogates toward o-benzoxylation of 2-phenylpyridine catalyzed by copper Organic Letters, 16 (6). pp. 1614-1617. ISSN 1523-7060
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Official URL: https://pubs.acs.org/doi/abs/10.1021/ol500224e
Related URL: http://dx.doi.org/10.1021/ol500224e
Abstract
A variety of styrenes and phenylacetylenes serve as excellent arylcarboxy sources in bringing about substrate directed o-benzoxylation of 2-phenylpyridine derivatives catalyzed by Cu(II) in the presence of TBHP. This reaction proceeds via formation of phenylglyoxal followed by decarbonylation to benzoyl radical/benzaldehyde which acts as the arylcarboxy source.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 113872 |
| Deposited On: | 02 May 2018 04:49 |
| Last Modified: | 02 May 2018 04:49 |
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