Rout, Saroj Kumar ; Guin, Srimanta ; Ali, Wajid ; Gogoi, Anupal ; Patel, Bhisma K. (2014) Copper-catalyzed esterification of alkylbenzenes with cyclic ethers and cycloalkanes via C(sp3)–H activation following cross-dehydrogenative coupling Organic Letters, 16 (11). pp. 3086-3089. ISSN 1523-7060
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Official URL: https://pubs.acs.org/doi/abs/10.1021/ol5011906
Related URL: http://dx.doi.org/10.1021/ol5011906
Abstract
A copper-catalyzed cross-dehydrogenative coupling strategy has been developed for the synthesis of two classes of esters from simple solvents. The reaction of methylarenes with cyclic ethers resulted in α-acyloxy ethers involving four sp3 C–H cleavages, while treatment of methylarenes with cycloalkanes led to the formation of allyl esters at the expense of six consecutive sp3 C–H bonds.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 113871 |
| Deposited On: | 30 Apr 2018 12:21 |
| Last Modified: | 30 Apr 2018 12:21 |
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