Behera, Ahalya ; Rout, Saroj K. ; Guin, Srimanta ; Patel, Bhisma K. (2014) Benzylamine as an arylcarboxy surrogate: a copper catalysed o-benzoxylation of 2-phenylpyridines using benzyl amines RSC Advances, 4 (98). pp. 55115-55118. ISSN 2046-2069
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Official URL: http://pubs.rsc.org/en/content/articlelanding/2014...
Related URL: http://dx.doi.org/10.1039/C4RA09922B
Abstract
Different reactivities and selectivities of Cu and Pd catalysts have been demonstrated in the reactions of benzylamines with 2-phenylpyridines. Although Pd is reported to give o-arylation (ArCO–), Cu introduces an arylcarboxy group (ArCOO–) at the proximal site of the directing group. For the first time benzylamine has been utilised as a synthetic equivalent of an arylcarboxy group.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 113859 |
| Deposited On: | 30 Apr 2018 12:11 |
| Last Modified: | 30 Apr 2018 12:11 |
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