Nano CuO Catalyzed Cross Dehydrogenative Coupling (CDC) of aldehydes to anhydrides

Khatun, Nilufa ; Santra, Sourav Kumar ; Banerjee, Arghya ; Patel, Bhisma K. (2015) Nano CuO Catalyzed Cross Dehydrogenative Coupling (CDC) of aldehydes to anhydrides European Journal of Organic Chemistry, 2015 (6). pp. 1309-1313. ISSN 1434-193X

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Official URL: https://onlinelibrary.wiley.com/doi/full/10.1002/e...

Related URL: http://dx.doi.org/10.1002/ejoc.201403508

Abstract

An elegant synthesis of carboxylic acid anhydrides has been developed directly from arylaldehydes using CuO nanoparticles as the catalyst and Tert‐butyl Hydroperoxide (TBHP) as the oxidant. During anhydride formation the reaction proceeds through a double sp2 C–H functionalization of aldehydes to generate two consecutive C–O bonds.

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ID Code:113818
Deposited On:02 May 2018 04:47
Last Modified:02 May 2018 04:47

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