Khatun, Nilufa ; Banerjee, Arghya ; Santra, Sourav Kumar ; Ali, Wajid ; Patel, Bhisma K. (2015) Benzylic ethers as arylcarboxy surrogates in substrate directed ortho C–H functionalisation catalysed by copper RSC Advances, 5 (46). pp. 36461-36466. ISSN 2046-2069
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Official URL: http://pubs.rsc.org/en/content/articlelanding/2015...
Related URL: http://dx.doi.org/10.1039/C5RA03462K
Abstract
A copper catalysed ortho-benzoxylation of 2-arylpyridines has been accomplished using benzylic ethers as the alternative arylcarboxy sources (ArCOO–) via sp2 C–H bond activation. The use of the Pd/TBHP catalytic system is reported to install an o-aroyl (ArCO–) moiety at the 2-arylpyridine while the Cu/TBHP combination fixes a benzoxy (ArCOO–) group at the ortho site.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 113812 |
| Deposited On: | 02 May 2018 04:46 |
| Last Modified: | 02 May 2018 04:46 |
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