Long range B-site cation ordering and Briet–Wigner–Fano line shape of A1g-like Raman mode in Nd1−xSmx(Mg0.5Ti0.5)O3 microwave dielectric ceramics

Kiran, S. Roopas ; Babu, G. Santosh ; Narayana, Chandrabhas ; Murthy, V. R. K. ; Subramanian, V. (2013) Long range B-site cation ordering and Briet–Wigner–Fano line shape of A1g-like Raman mode in Nd1−xSmx(Mg0.5Ti0.5)O3 microwave dielectric ceramics Materials Research Bulletin, 48 (2). pp. 194-199. ISSN 0025-5408

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Official URL: https://www.sciencedirect.com/science/article/pii/...

Related URL: http://dx.doi.org/10.1016/j.materresbull.2012.09.056

Abstract

Nd1−xSmx(Mg0.5Ti0.5)O3 (x = 0.0–1.0) samples were prepared by solid-state reaction method. Rietveld refinement of X-ray diffraction data was done using P21/n space group with monoclinic symmetry, which supports 1:1 B-site cation ordering. Long Range Ordering (LRO) parameter decreased up to x = 0.5 and then found to increase with further increase in Sm concentration. The A1g-like mode in Raman spectra was observed to possess Briet–Wigner–Fano line shape. The variation in obtained line width of the A1g-like mode supported LRO. Microwave dielectric characteristics such as dielectric constant (εr), quality factor (Q) and temperature coefficient of resonant frequency (τf) were measured in the range of 7–9 GHz. εr decreased from 26.5 to 24.9 and τf become less negative from −58 ppm/°C to −36 ppm/°C with increase in Sm concentration. Q × f decreased from 47,500 GHz (for x = 0) to 39,800 GHz (for x = 0.5) and then increased to 44,600 GHz (for x = 1).

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:C. X-ray Diffraction; C. Raman Spectroscopy; D. Dielectric Properties
ID Code:113675
Deposited On:23 Apr 2018 10:27
Last Modified:23 Apr 2018 10:27

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