A Brillouin study of the temperature-dependence of the acoustic modes across the insulator–metal transitions in V₂O₃ and Cr-doped V₂O₃

Abstract

Brillouin scattering studies have been carried out on high-quality single crystals of undoped and 0.9% Cr-doped V₂O₃. The observed modes in both the samples at ∼12 and ∼60 GHz are associated with the Surface Rayleigh Wave (SRW) and Bulk Acoustic Wave (BAW), respectively. In the undoped sample, the mode frequencies of the SRW and BAW modes decrease as the temperature is lowered from room temperature to the insulator–metal transition temperature (T_IM = T_N = ∼130 K). Below the transition, the modes show hardening. In the doped sample, the SRW mode shows a similar temperature-dependence as the undoped one, but the BAW mode shows hardening from room temperature down to the lowest temperature (50 K). This is the first measurement of the sound velocity below T_IM in the V₂O₃ system. The softening of the SRW frequency from 330 K to T_IM can be qualitatively understood on the basis of the temperature-dependence of C₄₄, which, in turn, is related to the orbital fluctuations in the paramagnetic metallic phase. The hardening of the mode frequencies below T_IM suggests that C₄₄ must increase in the antiferromagnetic insulating phase, possibly due to the orbital ordering.