A bimodal anionic MOF: turn-off sensing of CuII and specific sensitization of EuIII

Bhattacharyya, Sohini ; Chakraborty, Anindita ; Jayaramulu, Kolleboyina ; Hazra, Arpan ; Maji, Tapas Kumar (2014) A bimodal anionic MOF: turn-off sensing of CuII and specific sensitization of EuIII Chemical Communications, 50 (88). pp. 13567-13570. ISSN 1359-7345

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Official URL: http://pubs.rsc.org/en/content/articlelanding/2014...

Related URL: http://dx.doi.org/10.1039/C4CC05991C

Abstract

A novel porous anionic MOF {[Mg3(ndc)2.5(HCO2)2(H2O)][NH2Me2]·2H2O·DMF} (1) having exchangeable dimethyl amine cations in 1D channels has been synthesized and characterized. Through cation exchange, 1 manifests bimodal functionality, being a turn-off sensor of CuII on one hand, and a selective sensitizer of EuIII emitting intense pure red emission on the other.

Item Type:Article
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ID Code:113563
Deposited On:29 May 2018 09:07
Last Modified:29 May 2018 09:07

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