Jena, Rajesh K. ; Rajesh, Y. ; Mandal, Mahitosh ; Bhattacharjee, Manish (2017) [(para‐Cymene)Ru(dppp)Cl][PF6]‐catalysed stereospecific synthesis of O‐dienyl esters and evaluation of the anticancer activity of a long‐chain fatty acid O‐dienyl ester European Journal of Organic Chemistry, 2017 (11). pp. 1514-1519. ISSN 1434-193X
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Official URL: https://onlinelibrary.wiley.com/doi/abs/10.1002/ej...
Related URL: http://dx.doi.org/10.1002/ejoc.201601557
Abstract
O‐Dienyl esters are obtained through the regio‐ and stereospecific addition of both aromatic and aliphatic carboxylic acids to terminal propargylic alcohols, with the sequential formation of a carbon–oxygen bond and dehydration, in the presence of [(p‐cymene)Ru(dppp)Cl][PF6] (1). Also, the cytotoxicity and anticancer activity of the newly synthesized O‐dienyl ester (Z)‐3‐methylbuta‐1,3‐dienyl oleate have been investigated.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons Inc. |
| Keywords: | Ruthenium; Alkynes; Esters; Propargylic Compounds; Carboxylic Acids; Fatty Acids |
| ID Code: | 113417 |
| Deposited On: | 08 May 2018 07:05 |
| Last Modified: | 08 May 2018 07:05 |
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