Pirotta, S. ; Xu, X. G. ; Delfan, A. ; Mysore, S. ; Maiti, S. ; Dacarro, G. ; Patrini, M. ; Galli, M. ; Guizzetti, G. ; Bajoni, D. ; Sipe, J. E. ; Walker, G. C. ; Liscidini, M. (2013) Surface-enhanced Raman scattering in purely dielectric structures via Bloch surface waves Journal of Physical Chemistry C, 117 (13). pp. 6821-6825. ISSN 1932-7447
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Official URL: https://pubs.acs.org/doi/abs/10.1021/jp400223f
Related URL: http://dx.doi.org/10.1021/jp400223f
Abstract
We study surface-enhanced Raman scattering (SERS) in fully dielectric periodic structures supporting Bloch surface waves. We demonstrate a lower bound for the SERS enhancement of 50 when the optical pump is resonantly coupled to the Bloch surface wave supported by the structure. A corresponding photoluminescence experiment shows an emission enhancement of more than two orders of magnitude, suggesting that the actual SERS enhancement is ∼200. Analogous conclusions are obtained by means of a semiclassical theoretical model. These results suggest an alternative to plasmonic materials to enhance Raman scattering at a surface and are of interest to those working in the field of Raman as well as fluorescence spectroscopy.
Item Type: | Article |
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Source: | Copyright of this article belongs to American Chemical Society. |
ID Code: | 112982 |
Deposited On: | 24 May 2018 09:35 |
Last Modified: | 24 May 2018 09:35 |
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