Adarsh, N. N. ; Kumar, D. Krishna ; Dastidar, Parthasarathi (2008) Ligating topology and counter anion controlled formation of discrete metallo-macrocycle and 2D corrugated sheet in coordination compounds derived from a bis-pyridyl-bis-amide ligand and Cd (II)salts Inorganic Chemistry Communications, 11 (6). pp. 636-642. ISSN 1387-7003
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Official URL: https://www.sciencedirect.com/science/article/pii/...
Related URL: http://dx.doi.org/10.1016/j.inoche.2008.02.024
Abstract
Two coordination compounds namely [{(H2O)2(NO3)4(MeOH)2Cd2(μ-L1)2}] 1 and [{(H2O)2Cd(μ-SO4)(μ-L1)}]n2 have been isolated by reacting a bis-pyridyl-bis-amide ligand namely N,N′-bis-(3-pyridyl)isophthalamide L1 with Cd(NO3)2 and CdSO4, respectively. Single crystals of both 1 and 2 were determined. It was revealed from the X-ray analyses that conformation dependent ligating topology of L1 and different coordination modes of the counter anions (nitrate and sulfate) are responsible for the formation of discrete metallo-macrocycle (compound 1) and 2D corrugated sheet (compound 2).
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Crystal Engineering; MOFs; Ligating Topology; Anion Control; X-Ray Crystallography |
| ID Code: | 112816 |
| Deposited On: | 23 Apr 2018 06:33 |
| Last Modified: | 23 Apr 2018 06:33 |
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