Trivedi, Darshak R. ; Dastidar, Parthasarathi (2006) Supramolecular hydrogen bond isomerism in organic salts: A transition from 0D to 1D Crystal Growth & Design, 6 (4). pp. 1022-1026. ISSN 1528-7483
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Official URL: https://pubs.acs.org/doi/10.1021/cg050674r
Related URL: http://dx.doi.org/10.1021/cg050674r
Abstract
Based on nine single-crystal structures of a series of organic salts derived from dicyclohexylamine and n-alkyl monocarboxylic acids (CH3−(CH2)n−COOH, n = 1−17), it is shown that salts having n = 14 and 15 display 1D hydrogen-bonded networks, whereas majority of the salts having n = 1−9 show 0D networks. Structural analyses indicate that both intra- and internetwork alkyl−alkyl interactions appear to be responsible for such a supramolecular transition.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 112518 |
| Deposited On: | 19 Apr 2018 11:51 |
| Last Modified: | 19 Apr 2018 11:51 |
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