Colloidal Fe-doped ZnO nanocrystals: facile low temperature synthesis, characterization and properties

Singhal, A. ; Achary, S. N. ; Tyagi, A. K. ; Manna, P. K. ; Yusuf, S. M. (2008) Colloidal Fe-doped ZnO nanocrystals: facile low temperature synthesis, characterization and properties Materials Science and Engineering B, 153 (1-3). pp. 47-52. ISSN 0921-5107

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.mseb.2008.09.030

Abstract

Colloidal Fe-doped ZnO nanocrystals, Zn1−xFexO (x = 0.00, 0.05, 0.07 and 0.1) have been prepared by thermal decomposition of metal precursors at 200 °C with hexadecylamine (HDA) as solvent and surfactant. The nanocrystals so prepared can be easily dispersed in non-polar solvents like chloroform and toluene. The nanocrystals have been structurally characterized using X-ray diffraction (XRD), high resolution transmission electron microscopy (HRTEM), energy dispersive X-ray analysis (EDX) and X-ray photoelectron spectroscopy (XPS). Magnetization measurements on a representative sample, Zn0.95Fe0.05O using a vibrating sample magnetometer (VSM) reveal that the nanocrystals exhibit a weak ferromagnetic behavior at 300 K. This observation is further confirmed by the electron paramagnetic resonance spectrum of Zn0.95Fe0.05O nanocrystals, which shows a distinct ferromagnetic resonance signal at room temperature.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Spintronics; Dilute Magnetic Semiconductor; Ferromagnetism; X-Ray Diffraction; Transmission Electron Microscopy
ID Code:112338
Deposited On:01 Dec 2017 12:05
Last Modified:01 Dec 2017 12:05

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