Magnetism of the spin-chain compound Ca3Co1.9Fe0.1O6: magnetization and neutron diffraction study

Jain, A. ; Yusuf, S. M. ; Campo, J. ; Keller, L. (2010) Magnetism of the spin-chain compound Ca3Co1.9Fe0.1O6: magnetization and neutron diffraction study Journal of Physics: Conference Series, 200 (2). Article ID 022021. ISSN 1742-6588

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Official URL: http://iopscience.iop.org/article/10.1088/1742-659...

Related URL: http://dx.doi.org/10.1088/1742-6596/200/2/022021

Abstract

We report the results of the dc magnetization and neutron diffraction studies of the quasi-one-dimensional spin-chain compound Ca3Co1.9Fe0.1O6. Rietveld refinement of neutron powder diffraction pattern at 100 K confirmed that Fe ion was located at trigonal prism site 6a (0, 0, 1/4). The dc susceptibility obeys the Curie-Weiss law. The appearance of additional magnetic Bragg peaks in the low temperature neutron powder diffraction patterns mainly indicates an antiferromagnetic ordering. The magnetic reflections can be indexed with a propagation vector K = (0, 0, 1), referred to the space group R3c (hexagonal setting), and indicate that the centering translations have been lost in the magnetic structure.

Item Type:Article
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ID Code:112319
Deposited On:01 Dec 2017 11:48
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