Structural, chemical and magnetic investigations of polycrystalline Zn_1-xMn_xO

Abstract

Present study reports the detailed structural and magnetic, as well as chemical analysis of polycrystalline Zn_1-xMn_xO (where x = 0, 0.005, 0.01, 0.03, 0.05 and 0.1) samples synthesized by the high-temperature solid state reaction route. X-ray diffraction studies reveal the presence of secondary phase for higher Mn-doping concentrations (x≥0.03). Secondary phase formation having spinel structure is confirmed and reported as an evidence for the first time using transmission electron microscopy study. Chemical investigations using X-ray photoelectron spectroscopy showed the presence of Mn in two valence states. From the observed results we are of the opinion that Zn²⁺ ions, mainly present at or near grain boundaries, diffuse into manganese oxide to form a stable spinel phase Zn_xMn_3−xO₄ at or near the grain boundaries of ZnO/Zn_1-xMn_xO. Magnetization measurements did not show any magnetic transition down to 5 K.