Samanta, Alok ; Ghosh, Swapan K. (2001) A theoretical study of electron transfer in nanoparticle-catalysed redox reactions Chemical Physics Letters, 349 (5-6). pp. 483-488. ISSN 0009-2614
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00092...
Related URL: http://dx.doi.org/10.1016/S0009-2614(01)01240-4
Abstract
Nanoparticle-catalysed electron transfer reactions have been investigated by using an extended version of the theory of electron transfer reactions for the bridge-mediated three-centre process and approximate expressions for various free energy quantities as well as the matrix elements. It is observed that the calculated rates for nanoparticle-catalysed reactions for the reduction of various dyes by standard reducing agents are considerably higher than the rates of direct electron transfer processes and are also found to agree quite well with recently reported experimental results.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 11195 |
| Deposited On: | 09 Nov 2010 03:50 |
| Last Modified: | 02 Jun 2011 10:01 |
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