Mukherjee, Soumya ; Manna, Biplab ; Desai, Aamod V. ; Yin, Yuefeng ; Krishna, Rajamani ; Babarao, Ravichandar ; Ghosh, Sujit K. (2016) Harnessing Lewis acidic open metal sites of metal–organic frameworks: the foremost route to achieve highly selective benzene sorption over cyclohexane Chemical Communications, 52 (53). pp. 8215-8218. ISSN 1359-7345
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Official URL: http://pubs.rsc.org/en/content/articlelanding/2016...
Related URL: http://dx.doi.org/10.1039/C6CC03015G
Abstract
π-Complexation triggered Lewis acid–base interactions between Open Metal Sites (OMS) of Metal–organic Frameworks (MOFs) and π-e− rich adsorptive Benzene (Bz) is exploited to establish M-MOF-74 as the best Bz-selective MOF sorbent, marking the first report of utilizing OMS behind benzene/cyclohexane separation; a key advance from the energy-economy standpoint of industrial separation.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 111942 |
| Deposited On: | 25 Sep 2017 12:57 |
| Last Modified: | 25 Sep 2017 12:57 |
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