UTSA-74: a MOF-74 isomer with two accessible binding sites per metal center for highly selective gas separation

Abstract

A new metal-organic framework Zn₂(H₂O)(dobdc)•0.5(H₂O) (UTSA-74, H4dobdc = 2,5-dioxido-1,4-benzenedicarboxylic acid), Zn-MOF-74/CPO-27-Zn isomer, has been synthesized and structurally characterized. It has a novel four coordinated fgl topology with one-dimensional channels of about 8.0 Å. Unlike metal sites in the well-established MOF-74 with a rod-packing structure in which each of them is in a five coordinate square pyramidal coordination geometry, there are two different Zn²⁺ sites within the binuclear secondary building units in UTSA-74 in which one of them (Zn1) is in a tetrahedral while another (Zn²) in an octahedral coordination geometry. After activation, the two axial water molecules on Zn² sites can be removed, generating UTSA-74a with two accessible gas binding sites per Zn² ion. Accordingly, UTSA-74a takes up a moderately high and comparable amount of acetylene (145 cm³/cm³) to Zn-MOF-74. Interestingly, the accessible Zn²⁺ sites in UTSA-74a are bridged by carbon dioxide molecules instead of being terminally bound in Zn-MOF-74, so UTSA-74a adsorbs a much smaller amount of carbon dioxide (90 cm³/cm³) than Zn-MOF-74 (146 cm³/cm³) at room temperature and 1 bar, leading to a superior MOF material for highly selective C₂H₂/CO₂ separation. X-ray crystal structures, gas sorption isotherms, molecular modeling, and simulated and experimental breakthroughs comprehensively support this result.