Yadav, G. D. ; Manjula Devi, K. (2001) A kinetic model for the enzyme-catalyzed self-epoxidation of oleic acid Journal of the American Oil Chemists' Society, 78 (4). pp. 347-351. ISSN 0003-021X
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Official URL: https://link.springer.com/article/10.1007/s11746-0...
Related URL: http://dx.doi.org/10.1007/s11746-001-0267-2
Abstract
This paper reports a kinetic model for the selfepoxidation of oleic acid with toluene as solvent and Novozym 435 (a commercially available preparation of immobilized Candida antarctica lipase) as catalyst at 30°C. The effects of various parameters on the conversion and rates of reaction were studied. Both the initial rate and the progress curve data were used to fit an ordered bi-bi model. At low temperatures, the rate of epoxidation was faster than the rate of deactivation of the enzyme by hydrogen peroxide.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Springer Verlag. |
| Keywords: | Chemical Kinetics; Enzyme Deactivation; Immobilized Lipase; Oleic Acid; Self-Epoxidation |
| ID Code: | 111866 |
| Deposited On: | 18 Sep 2017 12:23 |
| Last Modified: | 18 Sep 2017 12:23 |
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