Enhanced CO2 sorption and selectivity by functionalization of a NbO-type metal–organic framework with polarized benzothiadiazole moieties

Song, Chengling ; He, Yabing ; Li, Bin ; Ling, Yajing ; Wang, Hailong ; Feng, Yunlong ; Krishna, Rajamani ; Chen, Banglin (2014) Enhanced CO2 sorption and selectivity by functionalization of a NbO-type metal–organic framework with polarized benzothiadiazole moieties Chemical Communications, 50 (81). pp. 12105-12108. ISSN 1359-7345

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Official URL: http://pubs.rsc.org/en/content/articlelanding/2014...

Related URL: http://dx.doi.org/10.1039/C4CC05833J

Abstract

A new NbO-type metal–organic framework ZJNU-40 incorporating highly polarized benzothiadiazole moieties exhibits a high CO2 uptake of 108 cm3 g-1 at 296 K and 1 atm, as well as good adsorption selectivities of CO2 over CH4 and N2 at room temperature, which is superior to that of the analogous MOF NOTT-101.

Item Type:Article
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