Geetharani, K. ; Bose, Shubhankar Kumar ; Ghosh, Sundargopal (2012) Heterometallic cubane-type clusters containing group 13 and 16 elements Pure and Applied Chemistry, 84 (11). No pp. given. ISSN 0033-4545
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Official URL: https://www.degruyter.com/view/j/pac.2012.84.issue...
Related URL: http://dx.doi.org/10.1351/PAC-CON-11-10-17
Abstract
Heterometallic cubane-type clusters were synthesized from the reaction of group 6 and 8 metallaboranes using transition-metal carbonyl compounds. Structural and spectroscopic study revealed the existence of novel “capped-cubane” geometry. In addition, the crystal structure of these clusters distinctly confirms the presence of boride unit as one of the vertices. These clusters possess 60 cluster valence electrons (cve) and six metal–metal bonds. A plausible pathway for the formation of ruthenium-capped cubane has been described.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Walter de Gruyter GmbH & Co. KG. |
| Keywords: | Boranes; Boride; Cluster Compounds; Cubane; Iron; Metallaboranes; Molybdenum; Ruthenium; Selenium |
| ID Code: | 111012 |
| Deposited On: | 31 Jan 2018 12:32 |
| Last Modified: | 31 Jan 2018 12:32 |
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