Ferromagnetic-dielectric Ni_0.5Zn_0.5Fe_1.9O₄−δ/PbZr_0.52Ti_0.48O₃ particulate composites: electric, magnetic, mechanical, and electromagnetic properties

Abstract

Novel ferromagnetic-dielectric particulate composites of Ni_0.5Zn_0.5Fe_1.95O_4−δ (NZF) and PbZr_0.52Ti_0.48O₃ (PZT) were prepared by conventional ceramic method. The presence of two phases in composites was confirmed by XRD technique. The variations of dielectric constant (ε) with frequency in the range of 100 kHz–1 MHz at room temperature and also with temperature at three different frequencies (50 kHz, 100 kHz and 500 kHz) were studied. Detailed studies on the dielectric properties were done confirming that the magnetoelectric interaction between the constituent phases may result in various anomalies in the dielectric behaviour of the composites. It is proposed that interfaces play an important role in the dielectric properties, causing space charge effects and Maxwell-Wagner relaxation, particularly at low frequencies and high temperatures. The piezoelectric d₃₃ constant was studied at room temperature and the d₃₃ constant value decreased with ferrite content. Magnetic properties like B-H loops traces were studied to understand the saturation magnetic (M_s) and magnetic moment (μ_B) of the present particulate composites. The Magnetoelectric (ME) output was measured by varying dc bias magnetic field. A large ME output signal of 2780 mV/cm Oe was observed in the composite having 50% ferrite. The temperature variation of longitudinal modulus (L) and internal friction (Q⁻¹) of these particulate composites at 104 kHz was studied in the temperature range 30°C–420°C by the composite oscillator technique. Longitudinal modulus showed a sharp minimum and internal friction exhibits a sharp peak at ferroelectric-paraelectric phase transition. These ferroelectric-dielectric particulate composites were prepared with a view to using them as ME sensors and transducers.