Bera, A. K. ; Yusuf, S. M. ; Kumar, Amit ; Majumder, M. ; Ghoshray, K. ; Keller, L. (2016) Long-range and short-range magnetic correlations, and microscopic origin of net magnetization in the spin-1 trimer chain compound CaNi3P4O14 Physical Review B, 93 (18). Article ID 184409. ISSN 2469-9950
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Official URL: https://journals.aps.org/prb/abstract/10.1103/Phys...
Related URL: http://dx.doi.org/10.1103/PhysRevB.93.184409
Abstract
Spin-spin correlations and microscopic origin of net magnetization in the spin-1 trimer chain compound CaNi3P4O14 have been investigated by powder neutron diffraction. The present study reveals a three-dimensional long-range magnetic ordering below 16 K where the magnetic structure consists of ferromagnetic trimers that are coupled ferromagnetically along the spin-chain direction (b axis). The moment components along the a and c axes arrange antiferromagnetically. Our study establishes that the uncompensated moment components along the b axis (mb) result in a net magnetization per unit cell. The magnetic structure, determined in the present study, is in agreement with the results of recent first-principles calculation; however, it is in contrast to a fascinating experimental prediction of ferrimagnetic ordering based on the periodicity of the exchange interactions in CaNi3P4O14. Our study also confirms the presence of broad diffuse magnetic scattering, due to one-dimensional short-range spin-spin correlations, over a wide temperature range below ∼50 K down to a temperature well below the Tc. Total neutron scattering analysis by the reverse Monte Carlo (RMC) method reveals that the dominating spin-spin correlation above Tc is ferromagnetic and along the b axis. The nearest-neighbor spin-spin correlations along the a and c axes are found to be weakly antiferromagnetic. The nature of the trimer spin structure of the short-range ordered state (above Tc) is similar to that of the 3D long-range ordered state (below Tc). The present investigation of microscopic nature of the magnetic ground state also explains the condition required for the 1/3 magnetization plateau to be observed in the trimer spin chains. In spite of the S=1 trimer chain system, the present compound CaNi3P4O14 is found to be a good realization of a three-dimensional magnet below Tc=16 K with full ordered moment values of ∼2 μB/Ni2+ (1.98 and 1.96μB/Ni2+ for two Ni sites, respectively) at 1.5 K.
Item Type: | Article |
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Source: | Copyright of this article belongs to American Physical Society. |
ID Code: | 110418 |
Deposited On: | 30 Nov 2017 12:00 |
Last Modified: | 01 Dec 2017 11:40 |
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