Dhurjati, Mudigonda S. K. ; Sarma, Jagarlapudi A. R. P. ; Desiraju, Gautam R. (1991) Unusual [2 + 2] topochemical cycloadditions of 3-cyano-and4-cyano-cinnamic acids: temperature dependent solid state photochemical reactions Chemical Communications (23). pp. 1702-1703. ISSN 1359-7345
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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/1991...
Related URL: http://dx.doi.org/10.1039/C39910001702
Abstract
The seeming difference in the topochemical [2 + 2] photoreactivity of 3-cyanocinnamic acid 1 and 4-cyanocinnamic acid 2 is caused by differing degrees of ease of molecular motion in the crystals and the unreactive 1 becomes reactive when heated to 130 °C
Item Type: | Article |
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Source: | Copyright of this article belongs to Royal Society of Chemistry. |
ID Code: | 11025 |
Deposited On: | 09 Nov 2010 04:15 |
Last Modified: | 28 May 2011 11:43 |
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