Jindal, Garima ; Sunoj, Raghavan B. (2012) Mechanistic insights into the role of chiral ligands in asymmetric diamination reactions Chemistry - A European Journal, 18 (23). pp. 7045-7049. ISSN 0947-6539
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/chem.20...
Related URL: http://dx.doi.org/10.1002/chem.201200872
Abstract
The most recent developments in Pd-catalyzed asymmetric syntheses of diamines by using phosphoramidite ligands offer promising avenues to access chiral diamines. The molecular-level insights on the transfer of chiral information from axially chiral binol-derived phosphoramidites to diamine products in Pd-catalyzed asymmetric diamination are presented. Through DFT studies, the origin of stereo- and regioselectivities in the asymmetric diamination of dienes is established.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons, Inc. |
| Keywords: | Density Functional Calculations; Diamination; Stereoselectivity; Transition States; Weak Interactions |
| ID Code: | 109843 |
| Deposited On: | 02 Aug 2017 09:28 |
| Last Modified: | 02 Aug 2017 09:28 |
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