Kotha, Sambasivarao ; Kashinath, Dhurke ; Lahiri, Kakali ; Sunoj, Raghavan B. (2004) Synthesis of C3-symmetric nano-sized polyaromatic compounds by trimerization and Suzuki−Miyaura cross-coupling reactions European Journal of Organic Chemistry, 2004 (19). pp. 4003-4013. ISSN 1434-193X
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/ejoc.20...
Related URL: http://dx.doi.org/10.1002/ejoc.200400257
Abstract
Various C3-symmetric molecules were prepared by trimerization of acetyl aromatic compounds and subsequently coupled with various boronic acids under Pd0 catalysis conditions to generate oligoaryl/-heteroaryl C3-symmetric molecules. Several furan- and thiophene-containing star-shaped molecules were prepared by the use of Suzuki−Miyaura cross-coupling as a key step. Structural and conformational details were explored by semi-empirical molecular orbital theory using the AM1 method.
Item Type: | Article |
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Source: | Copyright of this article belongs to John Wiley & Sons, Inc. |
Keywords: | C−C Coupling; Cyclotrimerizations; Nanostructures; Polycycles; Semi-empirical Calculations |
ID Code: | 109835 |
Deposited On: | 02 Aug 2017 11:16 |
Last Modified: | 02 Aug 2017 11:16 |
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