Krishna, Urlam Murali ; Patil, Mahendra P. ; Sunoj, Raghavan B. ; Trivedi, Girish K. (2010) [5+3] Cycloaddition of 3-oxidopyrylium: a novel route to functionalized cyclooctanoids from furans Synthesis, 2010 (02). pp. 320-328. ISSN 0039-7881
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Official URL: https://www.thieme-connect.de/DOI/DOI?10.1055/s-00...
Related URL: http://dx.doi.org/10.1055/s-0029-1217092
Abstract
We report a facile and efficient synthesis of highly functionalized cyclooctanoid derivatives by employing a dimerization reaction of 3-oxidopyrylium ylides. Different substituents are introduced on the dimer and the stereochemical outcome of the resultant cyclooctanoids is unambiguously established by single-crystal X-ray analysis.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Thieme Publishing. |
| Keywords: | Cyclooctanoids; 3-Oxidopyrylium Ylides; [5+3] Cycloadditions; Stereoselectivity; Density Functional Calculations |
| ID Code: | 109796 |
| Deposited On: | 02 Aug 2017 12:09 |
| Last Modified: | 02 Aug 2017 12:09 |
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