Jindal, Garima ; Sunoj, Raghavan B. (2014) Axially chiral imidodiphosphoric acid catalyst for asymmetric sulfoxidation reaction: insights on asymmetric induction Angewandte Chemie International Edition, 53 (17). pp. 4432-4436. ISSN 1433-7851
Full text not available from this repository.
Official URL: http://onlinelibrary.wiley.com/doi/10.1002/anie.20...
Related URL: http://dx.doi.org/10.1002/anie.201309532
Abstract
Insights into chiral induction for an asymmetric sulfoxidation reaction involving a single oxygen atom transfer are gained through analyzing the stereocontrolling transition states. The fitting of the substrate into the chiral cavity of a new class of imidodiphosphoric Bronsted acids, as well as weak C-H⋅⋅⋅π and C-H⋅⋅⋅O noncovalent interactions, are identified as responsible for the observed chiral induction.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons, Inc. |
| Keywords: | Asymmetric Catalysis; Bronsted Acids; Density Functional calculations; Noncovalent Interactions; Transition States |
| ID Code: | 109747 |
| Deposited On: | 02 Aug 2017 08:36 |
| Last Modified: | 02 Aug 2017 08:36 |
Repository Staff Only: item control page
