Kaur-Ghumaan, Sandeep ; Sreenithya, A. ; Sunoj, Raghavan B. (2015) Synthesis, characterization and DFT studies of 1, 1′-Bis(diphenylphosphino)ferrocene substituted diiron complexes: bioinspired [FeFe] hydrogenase model complexes Journal of Chemical Sciences, 127 (3). pp. 557-563. ISSN 0974-3626
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Official URL: http://www.ias.ac.in/describe/article/jcsc/127/03/...
Related URL: http://dx.doi.org/10.1007/s12039-015-0809-y
Abstract
The reaction of [Fe2(CO)6(μ-toluene-3, 4-benzenedithiolate)] 1 and bidentate diphosphine, 1, 1′-bis(diphenylphosphino)ferrocene (dppf) has been studied. New complexes obtained have been characterized by various spectroscopic techniques as bioinspired models of the iron hydrogenase active site. The crystal structure of [Fe2(CO)5(κ1-dppfO)(μ-toluene-3, 4-benzenedithiolate)] 4 is reported.
| Item Type: | Article |
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| Source: | Copyright of this article belongs to Indian Academy of Sciences. |
| Keywords: | Bioinorganic Chemistry; Hydrogenase Enzyme; Bidentate Phosphine; Proton Reduction; Redox Active Ligands; Density Functional Calculations |
| ID Code: | 109713 |
| Deposited On: | 02 Aug 2017 11:17 |
| Last Modified: | 03 Aug 2017 06:17 |
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