Desiraju, Gautam R. ; Kannan, V. (1986) What is the maximum yield in the solid state cinnamic acid dimerisation? A combinatorial mathematical approach Proceedings of the Indian Academy of Sciences - Chemical Sciences, 96 (5). pp. 351-362. ISSN 0253-4134
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Official URL: http://www.ias.ac.in/j_archive/chemsci/96/3/351-36...
Related URL: http://dx.doi.org/10.1007/BF02895731
Abstract
Recurrence relations have been employed to obtain the maximum possible theoretical conversion in a topochemically controlled organic solid state reaction. Experimental deviations from this analytical value of ≈82% reflect the importance of defects, molecular relaxation and surface phenomena in real crystals.
| Item Type: | Article |
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| Source: | Copyright of this article belongs to Indian Academy of Sciences. |
| Keywords: | Configuration; Recurrence Relation; Power Series; Partial Fractions; Topochemistry; Cinnamic Acid; Photodimerisation; Maximum Yield |
| ID Code: | 10967 |
| Deposited On: | 09 Nov 2010 04:24 |
| Last Modified: | 16 May 2016 20:29 |
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