Synthesis of shape-persistent polyal dendrimers - facile entry to polyene and polyyne dendrimers

Narayanan, Vijay ; Sankararaman, Sethuraman ; Hopf, Henning (2005) Synthesis of shape-persistent polyal dendrimers - facile entry to polyene and polyyne dendrimers European Journal of Organic Chemistry, 2005 (13). pp. 2740-2746. ISSN 1434-193X

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/ejoc.20...

Related URL: http://dx.doi.org/10.1002/ejoc.200500055

Abstract

Polyaldehyde (polyal) dendrimers were synthesized by a divergent iterative method using 1,3,5-triethynylbenzene (1) as the core unit and 2-bromo-5-tert-butyl-1,3-benzenedicarbaldehyde (2) as the building block. The polyal dendrimers were further transformed into a new class of polyene and polyyne dendrimers.

Item Type:Article
Source:Copyright of this article belongs to John Wiley and Sons, Inc.
Keywords:Dendrimers; Polyenes; Polyynes; Sonogashira Coupling; Corey–Fuchs Reaction
ID Code:109604
Deposited On:02 Aug 2017 12:59
Last Modified:02 Aug 2017 12:59

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