Corrosion of borosilicate glasses subjected to aggressive test conditions: structural investigations

Thorat, Vidya S. ; Mishra, Raman K. ; Kumaran, Sudarsan V. ; Kumar, Amar ; Vatsa, Rajesh K. ; Kaushik, Chetan P. ; Tyagi, Avesh K. (2016) Corrosion of borosilicate glasses subjected to aggressive test conditions: structural investigations Journal of American Ceramic Society, 99 (10). pp. 3251-3259. ISSN 0002-7820

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Official URL: http://onlinelibrary.wiley.com/doi/10.1111/jace.14...

Related URL: http://dx.doi.org/10.1111/jace.14340

Abstract

Sodium borosilicate (NBS) and barium sodium borosilicate (BBS) glasses, used for immobilization of high-level nuclear waste with compositions (SiO2)0.477(B2O3)0.239(Na2O)0.170(TiO2)0.023(CaO)0.068(Al2O3)0.023 and (SiO2)0.482(B2O3)0.244(Na2O)0.220(BaO)0.054 were subjected leaching experiments under hydrothermal conditions in an autoclave at 200°C for different time durations. Morphological and structural transformations associated with leaching, have been monitored with techniques like XRD, SEM, solid-state nuclear magnetic resonance. XRD and SEM along with NMR studies have confirmed that, upon leaching, formation of an aluminosilicate phase, Zeolite-P (Na6Al6Si10O32·12H2O), occurs with NBS glass. BBS glass upon subjecting to the same conditions leads to formation of multiple amorphous phases having Q4 (silica rich phase) and Q3 structural units of Silicon along with structurally modified residual glass. Upon leaching BO3 structural units preferentially get released from BBS glass. Comparison of results with international simple glass confirmed that, for the latter, mass loss rates are one order of magnitude lower.

Item Type:Article
Source:Copyright of this article belongs to John Wiley and Sons, Inc.
Keywords:Borosilicate Glass; Glass; Nuclear waste; Structure
ID Code:109337
Deposited On:01 Feb 2018 11:39
Last Modified:01 Feb 2018 11:39

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