Banerjee, Rahul ; Bhatt, Prashant M. ; Kirchner, Michael T. ; Desiraju, Gautam R. (2005) Structural studies of the system Na(saccharinate)·nH2O: a model for crystallization Angewandte Chemie International Edition, 44 (17). pp. 2515-2520. ISSN 1433-7851
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/anie.20...
Related URL: http://dx.doi.org/10.1002/anie.200462967
Abstract
Not far from a crystal nucleus? The complex crystal structure of sodium saccharin "dihydrate"could be a good model for nucleation (see graphic). The asymmetric unit contains 362 atoms and much water, and the crystal contains ordered and disordered regions. Amazingly, the crystal structure of this metastable compound was not determined for 125 years following its isolation, although it is manufactured in bulk.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons. |
| Keywords: | Hydrogen Bonds; Nucleation; Saccharin; Transition States; Water |
| ID Code: | 10911 |
| Deposited On: | 09 Nov 2010 04:32 |
| Last Modified: | 30 May 2011 05:15 |
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