Boucher, Benoît ; Ghosh, Sundargopal ; Halet, Jean-François ; Kahlal, Samia ; Saillard, Jean-Yves (2012) Bonding and electronic structure of Cp*2Ru2(B8H14), a metallaborane analogue of dinuclear pentalene complexes Journal of Organometallic Chemistry, 721-22 . pp. 167-172. ISSN 0022-328X
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.jorganchem.2012.08.033
Abstract
DFT calculations were carried out on compound Cp*2Ru2(B8H14) that suggests a strong link with the pentalene complex Cp*2Fe2(C8H6). Both compounds exhibit similar bonding modes and qualitatively related electronic structures. There are however, differences which are related to the weaker B–B bond in the B8H14 ligand as compared to the C–C bond in the pentalene ligand.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Cluster Compounds; Density Functional Theory Calculations; Iron; Metallaborane Complexes; Pentalene; Ruthenium |
| ID Code: | 108925 |
| Deposited On: | 31 Jan 2018 12:20 |
| Last Modified: | 31 Jan 2018 12:20 |
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