A triazole based triferrocene derivative as a multiresponsive chemosensor for Hg(II) ion and a redox chemosensor for H₂PO₄⁻ ion

Abstract

A triazole tethered triferrocene receptor, C₄₀H₄₀O₂N₆Fe₃ 3, has been synthesized from the reaction of mono-alkynyl substituted ferrocene, 1 and 1,1′-bis-(azidomethyl)ferrocene, 2. Consequently the cation and anion sensing properties of 3 have been examined. The receptor 3 was found to be highly selective electrochemical [Math Processing Error], optical and chromogenic chemosensor for Hg²⁺ ion in aqueous environment. The substantial changes in its absorption spectra are accompanied by the appearance of a new low-energy peak at 631 nm (ɛ = 3400 M⁻¹ cm⁻¹). This is also accompanied by a strong color change from yellow to purple, that allows a prospective for the “naked eye” detection of Hg²⁺ ion over other competitor cations such as Pb²⁺, Cd²⁺, Zn²⁺, etc. In addition, among various anions, 3 shows a distinct electrochemical recognition of dihydrogen phosphate anion by its multiple H-bonding (C–H⋯O), which is supported by electrochemical (large cathodic shift ΔE_1/2 = −175 mV) and ¹H NMR titration results.