A mechanistic study of the utilization of arachno-diruthenaborane [(Cp*RuCO)2B2H6] as an active alkyne-cyclotrimerization catalyst

Geetharani, K. ; Tussupbayev, Samat ; Borowka, Julia ; Holthausen, Max C. ; Ghosh, Sundargopal (2012) A mechanistic study of the utilization of arachno-diruthenaborane [(Cp*RuCO)2B2H6] as an active alkyne-cyclotrimerization catalyst Chemistry - A European Journal, 18 (27). pp. 8482-8489. ISSN 0947-6539

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/chem.20...

Related URL: http://dx.doi.org/10.1002/chem.201200291

Abstract

The reaction of nido-[1,2-(Cp*RuH)2B3H7] (1 a, Cp*=η5-C5Me5) with [Mo(CO)3(CH3CN)3] under mild conditions yields the new metallaborane arachno-[(Cp*RuCO)2B2H6] (2). Compound 2 catalyzes the cyclotrimerization of a variety of internal- and terminal alkynes to yield mixtures of 1,3,5- and 1,2,4-substituted benzenes. The reactivities of nido-1 a and arachno-2 with alkynes demonstrates that a change in geometry from nido to arachno drives a change in the reaction from alkyne-insertion to catalytic cyclotrimerization, respectively. Density functional calculations have been used to evaluate the reaction pathways of the cyclotrimerization of alkynes catalyzed by compound 2. The reaction involves the formation of a ruthenacyclic intermediate and the subsequent alkyne-insertion step is initiated by a [2+2] cycloaddition between this intermediate and an alkyne. The experimental and quantum-chemical results also show that the stability of the metallacyclic intermediate is strongly dependent on the nature of the substituents that are present on the alkyne.

Item Type:Article
Source:Copyright of this article belongs to John Wiley & Sons, Inc.
Keywords:Boron; Cyclotrimerization; Density Functional Calculations; Reaction Mechanisms; Ruthenium
ID Code:108844
Deposited On:31 Jan 2018 11:56
Last Modified:31 Jan 2018 11:56

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