Reactivity of diruthenium and dirhodium analogues of pentaborane(9): agostic versus boratrane complexes

Anju, R. S. ; Roy, Dipak Kumar ; Mondal, Bijan ; Yuvaraj, K. ; Arivazhagan, C. ; Saha, Koushik ; Varghese, Babu ; Ghosh, Sundargopal (2014) Reactivity of diruthenium and dirhodium analogues of pentaborane(9): agostic versus boratrane complexes Angewandte Chemie, 126 (11). pp. 2917-2921. ISSN 0044-8249

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/ange.20...

Related URL: http://dx.doi.org/10.1002/ange.201310416

Abstract

A series of novel Cp*-based (Cp*=η5-C5Me5) agostic, bis(σ-borate), and boratrane complexes have been synthesized from diruthenium and dirhodium analogues of pentaborane(9). The synthesis and structural characterization of the first neutral ruthenadiborane(6) analogue are also reported. This new route offers a very efficient method for the isolation of bis(σ-borate) and agostic complexes from diruthenapentaborane(9).

Item Type:Article
Source:Copyright of this article belongs to John Wiley & Sons, Inc.
Keywords:Agostische Borane; σ-Borane; Boratrane; Rhodium; Ruthenium
ID Code:108840
Deposited On:31 Jan 2018 11:55
Last Modified:31 Jan 2018 11:55

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