Ghosh, Sundargopal ; Shang, Maoyu ; Li, Yaping ; Fehlner, Thomas P. (2001) Synthesis of [(Cp*Re)2BnHn]n=8-10: metal boride particles that stretch the cluster structure paradigms Angewandte Chemie International Edition, 40 (6). pp. 1125-1128. ISSN 1433-7851
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/1521-37...
Related URL: http://dx.doi.org/10.1002/1521-3773(20010316)40:6<1125::AID-ANIE11250>3.0.CO;2-P
Abstract
Different cluster–structure electron-counting rules to those of either boranes or metallaboranes of later transition metals are obeyed by the metallaboranes formed from the earlier transition metals. This principle is confirmed by the existence and structures of the homologous series of rhenaboranes [(Cp*Re)2BnHn], n=7–10 (see scheme).
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley & Sons, Inc. |
| Keywords: | Boron; Carboranes; Cluster Compounds; Rhenium |
| ID Code: | 108835 |
| Deposited On: | 31 Jan 2018 11:56 |
| Last Modified: | 31 Jan 2018 11:56 |
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