High-yield synthesis of a hybrid 2,3,4,5-tetracarba-1,6-nido-hexaborane(6) cluster with an exo-polyhedral boracycle

Braunschweig, Holger ; Ghosh, Sundargopal ; Kupfer, Thomas ; Radacki, Krzysztof ; Wahler, Johannes (2011) High-yield synthesis of a hybrid 2,3,4,5-tetracarba-1,6-nido-hexaborane(6) cluster with an exo-polyhedral boracycle Chemistry - A European Journal, 17 (15). pp. 4081-4084. ISSN 0947-6539

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/chem.20...

Related URL: http://dx.doi.org/10.1002/chem.201100453

Abstract

Coupled cluster: An unprecedented 2,3,4,5-tetracarba-1,6-nido-hexaborane(6) cluster is accessible from a borole precursor in two steps involving a mild reduction process. The title compound consists of a perphenylated cluster framework, which is linked to an exo-polyhedral boracycle. This was confirmed by NMR spectroscopy and X-ray crystallography.

Item Type:Article
Source:Copyright of this article belongs to John Wiley & Sons, Inc.
Keywords:Borole; Boron; Nido-Carborane; Organoborane; Reduction
ID Code:108833
Deposited On:31 Jan 2018 11:56
Last Modified:31 Jan 2018 11:56

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