Ghosh, Sundargopal ; Lei, Xinjian ; Cahill, Christopher L. ; Fehlner, Thomas P. (2000) Symmetrical scission of the coordinated tetraborane in [(Cp*ReH2)2B4H4] on CO addition and reassociation of the coordinated diboranes on H2 loss Angewandte Chemie International Edition, 39 (16). pp. 2900-2902. ISSN 1433-7851
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/1521-37...
Related URL: http://dx.doi.org/10.1002/1521-3773(20000818)39:16<2900::AID-ANIE2900>3.0.CO;2-7
Abstract
The ready addition of CO to [(Cp*ReH2)2B4H4] (1) results in the cleavage of a B−B bond and formation of the structurally characterized isomers cis- and trans-2. The B−B bond is reformed, with loss of H2, on mild thermolysis to generate complex 3.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley & Sons, Inc. |
| Keywords: | Boranes; Carbonyl Complexes; Cluster Compounds; Hydrides; Rhenium |
| ID Code: | 108763 |
| Deposited On: | 31 Jan 2018 11:54 |
| Last Modified: | 31 Jan 2018 11:54 |
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