Boron beyond the icosahedral barrier: a 16-vertex metallaborane

Roy, Dipak Kumar ; Bose, Shubhankar Kumar ; Anju, R. S. ; Mondal, Bijan ; Ramkumar, V. ; Ghosh, Sundargopal (2013) Boron beyond the icosahedral barrier: a 16-vertex metallaborane Angewandte Chemie International Edition, 52 (11). pp. 3222-3226. ISSN 1433-7851

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/anie.20...

Related URL: http://dx.doi.org/10.1002/anie.201208849

Abstract

A neutral metallaborane comprising a Rh4B12 polyhedron with icosioctahedron geometry with 16 vertices and 28 triangular faces was prepared (see structure; Rh: red, B: green). The cage has the shape of a 12-membered truncated tetrahedron with four capped hexagonal faces.

Item Type:Article
Source:Copyright of this article belongs to John Wiley & Sons, Inc.
Keywords:Boron; Cage Compounds; Metallaboranes; Rhodium
ID Code:108760
Deposited On:31 Jan 2018 11:54
Last Modified:23 Nov 2022 10:06

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