Patil, Nitin T. ; Raut, Vivek S. ; Shinde, Valmik S. ; Gayatri, Gaddamanugu ; Sastry, G. Narahari (2012) Gold(I)-catalyzed unprecedented rearrangement reaction between 2-aminobenzaldehydes with propargyl amines: an expedient route to 3-aminoquinolines Chemistry - A European Journal, 18 (18). pp. 5530-5535. ISSN 0947-6539
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/chem.20...
Related URL: http://dx.doi.org/10.1002/chem.201103668
Abstract
Access to aminoquinolines: A gold(I)-catalyzed unprecedented rearrangement reaction between 2-aminobenzaldehydes with propargyl amine was studied. The study provided, for the first time, direct access to 3-aminoquinolines in one step starting from readily available starting materials (see scheme). Elegantly designed experiments were employed to unravel the mechanism of this unprecedented rearrangement, which are corroborated by DFT calculations.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons, Inc. |
| Keywords: | 3-aminoquinolines; Alkynes; Density Functional calculations; Gold; Rearrangement |
| ID Code: | 108523 |
| Deposited On: | 28 Jul 2017 04:48 |
| Last Modified: | 28 Jul 2017 04:48 |
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