Synthesis of s-fac/mer bis(N2-methyldiethylenetriamine, L) nickel(II): X-ray single crystal structures of s-fac[NiL2](NO3)2 and mer[NiL2](CF3CO2)2

Mondal, Arunendu ; Laskar, Inamur R. ; Chaudhuri, Nirmalendu Ray ; Mostafa, Golam ; Ghosh, Ashutosh ; Prasad, J. Shashidhara (1999) Synthesis of s-fac/mer bis(N2-methyldiethylenetriamine, L) nickel(II): X-ray single crystal structures of s-fac[NiL2](NO3)2 and mer[NiL2](CF3CO2)2 Transition Metal Chemistry, 24 (3). pp. 282-286. ISSN 0340-4285

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Official URL: https://link.springer.com/article/10.1023/A:100699...

Related URL: http://dx.doi.org/10.1023/A:1006999132388

Abstract

[NiL2](NO3)2 (1) and [NiL2](CF3CO2)2 (2) (L = N2-methyldiethylenetriamine] have been synthesized and their X-ray single crystal structures have been determined. The triamines are ligated to NiII s-facially in (1) and meridionally in (2), with a NiN6 chromophore in each complex.

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