Ray, Mau Sinha ; Ghosh, Ashutosh ; Mukhopadhyay, Gurucharan ; Drew, Michael G. B. (2003) Syntheses, characterization and x-ray crystal structures of copper (II) and nickel (II) complexes of tridentate monocondensed diamines Journal of Coordination Chemistry, 56 (13). pp. 1141-1148. ISSN 0095-8972
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Official URL: http://www.tandfonline.com/doi/abs/10.1080/0095897...
Related URL: http://dx.doi.org/10.1080/00958970310001601776
Abstract
The syntheses and characterization of three compounds involving tridentate “half-units” 7-amino-4-methyl-5-aza-3-hepten-2-one (HAMAH) and 8-amino-4-methyl-5-aza-3-octen-2-one (HAMAO) are described. Cu(II) and Ni(II) complexes with HAMAH have been isolated as four-coordinate complexes, the fourth coordination site being taken by imidazole, and have been structurally characterized. A Cu(II) complex involving HAMAO has been isolated as a highly insoluble polymeric species. Hydroxo bridging between the metal centres is indicated.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Taylor and Francis Ltd. |
| Keywords: | NO Donor; Tridentate; Schiff Base; Cu(II); Ni(II); X-ray Structure |
| ID Code: | 108405 |
| Deposited On: | 17 Oct 2017 12:59 |
| Last Modified: | 17 Oct 2017 12:59 |
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