Maity, Debdulal ; Chattopadhyay, Shouvik ; Ghosh, Ashutosh ; Drew, Michael G. B. ; Mukhopadhyay, Gurucharan (2009) Syntheses, characterization and X-ray crystal structures of Ni(II) complexes of tridentate monocondensed and tetradentate dicondensed Schiff bases Polyhedron, 28 (4). pp. 812-818. ISSN 0277-5387
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.poly.2008.12.015
Abstract
Two octahedral complexes [Ni(HL1)2](ClO4)2 (1) and [Ni(HL2)2](ClO4)2 (2) and a square planar complex [Ni(HL3)]ClO4 (3) have been prepared, where [HL1 = 3-(2-amino-ethylimino)-butan-2-one oxime, HL2 = 3-(2-amino-propylimino)butan-2-one oxime] and H2L3 = 3-[2-(3-hydroxy-1-methyl-but-2-enylideneamino)-1-methyl-ethylimino]-butan-2-one oxime. All the complexes have been characterized by elemental analyses, spectral studies and room temperature magnetic moment measurements. The molecular structures of all three compounds were elucidated on the basis of X-ray crystallography; complexes 1 and 2 are seen to be the mer isomers.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Ni(II) Complexes; Tridentate Schiff Base; Tetradentate Schiff Base; X-ray Structure; H-bonding |
| ID Code: | 108353 |
| Deposited On: | 13 Oct 2017 13:07 |
| Last Modified: | 13 Oct 2017 13:07 |
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