A ferromagnetic linear trinuclear Ni(II)-Schiff base complex supported by phenoxo and cinnamato bridges

Mukherjee, Pampa ; Drew, Michael G. B. ; Tangoulis, Vassilis ; Estrader, Marta ; Diaz, Carmen ; Ghosh, Ashutosh (2009) A ferromagnetic linear trinuclear Ni(II)-Schiff base complex supported by phenoxo and cinnamato bridges Inorganic Chemistry Communications, 12 (9). pp. 929-932. ISSN 1387-7003

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.inoche.2009.07.014

Abstract

A new linear trinuclear nickel (II) complex, [Ni3(salme)2(OCn)4] (Hsalme = 2-[(3-methylamino-propylimino)-methyl]-phenol, OCn = cinnamate), showing weak ferromagnetic coupling (J = 1.8(1) cm−1) through phenoxo and a novel tridentate bridging mode (1κ2OO′:2κO′) of the cinnamate ligand has been synthesized and structurally characterized by X-ray crystallography.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Nickel (II); Schiff Base; Bridging Cinnamate; X-ray Structure; Magnetic Properties
ID Code:108341
Deposited On:17 Oct 2017 12:58
Last Modified:17 Oct 2017 12:58

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