Biswas, Saptarshi ; Ghosh, Ashutosh (2012) A novel 1D chain of azido bridged copper (II) with a salen-type di-Schiff base ligand Journal of Molecular Structure, 1019 . pp. 32-36. ISSN 0022-2860
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.molstruc.2012.03.030
Abstract
One new complex of Cu(II), [(CuL) 2Cu3(N3)6]n (1) has been synthesized by reacting the “ligand complex”, [CuL] with copper acetate and sodium azide (NaN3) in methanol–water where the di-Schiff base ligand H2L = N,N′-bis(α-methylsalicylidene)-1,3-propanediamine. The X-ray single crystal structural analysis shows that complex 1 consists of an incomplete face-sharing double cube of four Cu (II) ions with the formula of [(CuL) 2Cu2(N3)2]2+ which are connected by [Cu(N3)4]2− unit to form a novel 1D chain.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Copper (II); di-Schiff Base Ligand; 1D Chain; Crystal Structure; Spectral Properties |
| ID Code: | 108293 |
| Deposited On: | 13 Oct 2017 13:08 |
| Last Modified: | 13 Oct 2017 13:08 |
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