Biswas, Rituparna ; Drew, Michael G. B. ; Ghosh, Ashutosh (2012) Synthesis and crystal structure of a novel octa-aqua bridged star-shaped Ni4K complex Inorganic Chemistry Communications, 24 . pp. 1-3. ISSN 1387-7003
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.inoche.2012.07.023
Abstract
A penta-nuclear, star-shaped hetero-metallic compound containing a unique Ni4 KO8 core has been synthesized. The X-ray single crystal structure analysis reveals that in the complex, [K(Ni(LH)2)4 (OH2)8](Br)(ClO4)8•1H2O (LH(CH3)2 HN+(CH2)3 NCHC6 H4 O−) the eight coordinate central K+ ion is encapsulated by four terminal [Ni(LH)2]2+ units through the double water bridges between K+ and each Ni(II) ions.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Heteronuclear Core; Ni(II)–K(I); Schiff base; X-Ray Analysis Star-shaped |
| ID Code: | 108284 |
| Deposited On: | 17 Oct 2017 13:00 |
| Last Modified: | 17 Oct 2017 13:00 |
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