Paul Singh Ishar, Mohan ; Singh, Gurpinder ; Elango, Munusamy ; Subramaniam, Venkatesan (2006) Regio- and exo-π-facial selective 1,3-dipolar cycloaddition of α-(3-pyridyl)-N-phenylnitrone to norbornadiene: activation of a π-bond of norbornadiene and control of regiochemistry of nitrone cycloaddition by nitrone addition to the other double bond Heterocycles, 68 (7). pp. 1409-1419. ISSN 0385-5414
Full text not available from this repository.
Official URL: https://www.heterocycles.jp/newlibrary/libraries/a...
Related URL: http://dx.doi.org/10.3987/COM-06-10732
Abstract
Thermal cycloaddition of α-(3-pyridyl)-N-phenylnitrone to a π-bond in norbornadiene not only activates the other double bond towards 1,3-dipolar cycloaddition, it also regulates the regiochemistry of addition leading to regio- and exo-π-facial selective formation of novel 2:1 cycloadducts. A DFT analysis in terms of the global and local reactivity indices affords a rationalization of the obtained results.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Japan Institute of Heterocyclic Chemistry. |
| ID Code: | 107780 |
| Deposited On: | 01 Dec 2017 12:16 |
| Last Modified: | 01 Dec 2017 12:16 |
Repository Staff Only: item control page
